1992 x-men: the animated series - season 1, episode 10

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Come The Apocalypse
After Apocalypse, immortal evil mutant, turns other mutant to be his Horsemen from a fictitious plot saying they would be cure - Famine, Pestilence, Wat and Death (Archangel). The Horsemen start chaos on the city and the X-men must battle the Horsemen to stop Apocalypse evil plan.